Dr. Volodymyr Smetana
Research Topic:
Complex Intermetallics; Open Framework Stuctures; Thermoelectrics; Ionic Liquid Structures
Contact: vs@bce.au.dk
Publications
- V. Babizhetskyy, J. Köhler, O. Myakush, V. Smetana, V. Levytskyy, A.-V. Mudring New intermetallics R1+xZr1−xNi (R = Ho–Tm, x ~ 0.5) with the TiNiSi type of structure. Intermetallics, 2021, 137, 107279. 10.1016/j.intermet.2021.107279
- B. Kotur, V. Babizhetskyy, V. Smetana, C. Zheng, A.-V. Mudring Crystal and electronic structures of the new ternary silicide Sc12Co41.8Si30.2. J. Solid State Chem., 2021, 302, 122373. 10.1016/j.jssc.2021.122373
- G. Bousrez, O. Renier, K. Stappert, B. Adranno, V. Smetana, K. Grübel, R. Kentsch, A.-V. Mudring, Ionic Liquid-Based Dye Sensitized Solar Cells – Insights into Electrolyte and Redox Mediator Design. ACS Sust. Chem. Eng., 2021, 9, 8107–8114. 10.1021/acssuschemeng.1c01057
- G. Bousrez, O. Renier, S. Kelley, B. Adranno, E. Tahavori, H. Titi, V. Smetana, S.-F. Tang, A.-V. Mudring, R. Rogers, Ready access to anhydrous anionic lanthanide acetates using imidazolium acetate ionic liquids as the reaction medium. Chem. Eur. J., 2021, 27. 10.1002/chem.202100141
- A. Nayak, V. Smetana, A.-V. Mudring, R. Rogers, Anhydrous vs Hydrated f‑Element Acetate Polymers Dictated by the 2 Stoichiometry of Protic Acidic/Basic Azole Mixtures. Cryst. Growth Des., 2021, 21, 2516-2525. 10.1021/acs.cgd.1c00181
- O. Renier, G. Bousrez, M. Yang, M. Hölter, B. Mallick, V. Smetana, A.-V. Mudring, Developing design tools for introducing and tuning structural order in ionic liquids. CrystEngComm, 2021, 23, 1785-1795. 10.1039/D0CE01672A
- V. Smetana, S. Kelley, H. Pei, A.-V. Mudring, R. Rogers, Sandwiched Kagomé Lattices in a Coordination Polymer Based on Mixed-Valent Uranium. Cryst. Growth Des., 2021, 21, 1727-1733. 10.1021/acs.cgd.0c01626
- S. Kelley, V. Smetana, A.-V. Mudring, R. Rogers, Structural Analysis of Mono-Substituted N-butyl-pyridinium Salts: In Search of Ionic Liquids. J. Coord. Chem., 2021, 74, 117-128. 10.1080/00958972.2021.1876851
- V. Babizhetskyy, Ya. Lomnytska, M. Dzevenko, C. Zheng, V. Smetana, A.-V. Mudring, Investigation in the ternary Ta-Ni-P system: Solid state phase equilibria at T=1070 K, crystal and electronic structures of new ternary phosphides. J. Alloys. Compd., 2021, 864, 158122. 10.1016/j.jallcom.2020.158122
- S. Pakhira, N. Sangeetha, V. Smetana, A.-V. Mudring, D. Johnston, Short-range ferromagnetic order due to Ir substitutions in single-crystalline Ba(Co1−xIrx)2As2 (0 ≤ x ≤ 0.25). J. Phys. Cond. Mat., 2020, 33, 115802. 10.1088/1361-648X/abd339
- T. Alammar, V. Smetana, H. Pei, I. Hamm, M. Wark, A.-V. Mudring, The Power of Ionic Liquids: Crystal Facet Engineering of SrTiO3 Nanoparticles for Tailored Photocatalytic Applications. Adv. Sust. Sys., 2021, 5, 2000180. 10.1002/adsu.202000180
- J. Namanga, H. Pei, G. Bousrez, V. Smetana, N. Gerlitzki, A.-V. Mudring, Fluorinated Cationic Iridium(III) Complex Yielding an Exceptional, Efficient, and Long-Lived Red-Light-Emitting Electrochemical Cell. Appl. Energy. Mater., 2020, 3, 9271-9277. 10.1021/acsaem.0c01600
- D. Prodius, M. Klocke, V. Smetana, T. Alammar, M. Garcia, T. Windus, I. Nlebedim, A.-V. Mudring, Rationally designed rare earth separation by selective oxalate solubilization. Chem. Commun., 2020, 56, 11386-11389. 10.1039/D0CC02270E
- K. Richter, K. Dorn, V. Smetana, A.-V. Mudring, Elucidating structure–property relationships in imidazolium-based halide ionic liquids: crystal structures and thermal behavior. Z. Kristallogr., 2020, 235, 365-374. 10.1515/zkri-2020-0046
- S. Siebeneichler, K. Dorn, V. Smetana, M. Valldor, A.-V. Mudring, A soft chemistry approach to the synthesis of single crystalline and highly pure (NH4)CoF3 for optical and magnetic investigations. J.Chem.Phys., 2020, 153, 104501. 10.1063/5.0023343
- N. Sangeetha, S. Pakhira, D. Ryan, V. Smetana, A.-V. Mudring, D. Johnston, Magnetic phase transitions in Eu(Co1−xNix)2−yAs2 single crystals. Phys. Rev. Mater., 2020, 4, 084407. 10.1103/PhysRevMaterials.4.084407
- J. Namanga, H. Pei, G. Bousrez, B. Mallick, V. Smetana, N. Gerlitzki, A.-V. Mudring, Efficient and Long Lived Green Light‐Emitting Electrochemical Cells. Adv. Funct. Mater., 2020, 30, 1909809. 10.1002/adfm.201909809
- T. Bell, V. Smetana, A.-V. Mudring, G. Meyer, Binary Intermetallics in the 70 atom % R Region of Two R−Pd Systems (R = Tb and Er): Hidden, Obscured, or Nonexistent? Inorg. Chem., 2020, 59, 10802-10812. 10.1021/acs.inorgchem.0c01311
- M. Mishra, S. Kelley, V. Smetana, D. Dixon, A. McNeill, A.-V. Mudring, R. Rogers, Crystallographic evidence of Watson–Crick connectivity in the base pair of anionic adenine with thymine. Proc. Natl. Acad. Sci., 2020, 117, 18224-18230. 10.1073/pnas.2008379117
- S. Pakhira, N. Sangeetha, V. Smetana, A.-V. Mudring, D. Johnston, Ferromagnetic cluster-glass phase in Ca(Co1−xIrx)2−yAs2 crystals. Phys. Rev. B, 2020, 102, 024410. 10.1103/PhysRevB.102.024410
- M. Rhodehouse, V. Smetana, C. Celania, A.-V. Mudring, G. Meyer, Ternary Polar Intermetallics within the Pt/Sn/R Systems (R = La–Sm): Stannides or Platinides? Inorg. Chem., 2020, 56, 7352-7359. 10.1021/acs.inorgchem.0c00884
- S.-F. Tang, V. Smetana, M. Mishra, S. Kelley, O. Renier, R. Rogers, A.-V. Mudring, Forcing Dicyanamide Coordination to f-Elements by Dissolution in Dicyanamide-Based Ionic Liquids. Inorg. Chem., 2020, 56, 7227-7237. 10.1021/acs.inorgchem.0c00667
- S. Kelley, V. Smetana, S. Emerson, A.-V. Mudring, R. Rogers Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids. Chem. Commun., 2020, 56, 4232-4235. 10.1039/C9CC09852F
- S. Kelley, V. Smetana, J. Nuss, D. Dixon, M. Vasiliu, A.-V. Mudring, R. Rogers, Dehydration of UO2Cl2·3H2O and Nd(NO3)3·6H2O with a Soft Donor Ligand and Comparison of Their Interactions through X‑ray Diffraction and Theoretical Investigation. Inorg. Chem., 2020, 59, 2861-2869. 10.1021/acs.inorgchem.9b03228
- F. Guillou, D. Paudyal, Y. Mudryk, A. Pathak, V. Smetana, A.-V.Mudring, V.K. Pecharsky, Metamagnetic transition, magnetocaloric effect and electronic structure of the rare-earth anti-perovskite SnOEu3. J. Magn. Magn. Mater., 2020, 501, 166405. 10.1016/j.jmmm.2020.166405
- A. Ovchinnikov, V. Smetana, A.-V. Mudring, Metallic alloys at the edge of complexity: structural aspects, chemical bonding and physical properties. J. Phys. Cond. Mat., 2020, 32, 243002. 10.1088/1361-648X/ab6b87
- S. Kelley, H. Pei, V. Smetana, A.-V. Mudring, R. Rogers, Structural Consequences of Halogen Bonding in Dialkylimidazolium: A New Design Strategy for Ionic Liquids Illustrated with the I2 Co-Crystal and Acetonitrile Solvate of 1,3-Dimethylimidazolium Iodide. Cryst. Growth Des., 2020, 20, 498–505. 10.1021/acs.cgd.9b01454
- V. Smetana, S. Kelley, H. Titi, X. Hou, S.-F. Tang, A.-V. Mudring, R. Rogers, Synthesis of Anhydrous Acetates for the Components of Nuclear 2 Fuel Recycling in Dialkylimidazolium Acetate Ionic Liquids. Inorg. Chem., 2020, 59, 818–828. 10.1021/acs.inorgchem.9b03077
- O. Renier, G. Bousrez, K. Stappert, M. Wilk-Kozubek, B. Adranno, H. Pei, E. Spielberg, V. Smetana, A.-V. Mudring, Photoisomerization and mesophase formation in azo-ionic liquids. Cryst. Growth Des., 2020, 20, 214–225. 10.1021/acs.cgd.9b01018
- V. Babizhetskyy, V. Levytskyy, V. Smetana, M. Wilk-Kozubek, O. Tsisar, L. Piskach, O. Parasyuk, A.-V. Mudring, New cation-disordered quaternary selenides Tl2Ga2TtSe6 (Tt = Ge, Sn). Z. Naturforsch. B., 2020, 75, 135–142. 10.1515/znb-2019-0169
- V. Smetana, S. Kelley, A.-V. Mudring, R. Rogers, A Five-Fold UO22+ Node is a Path to Dodecagonal Quasicrystal Approximants in Coordination Polymers. Sci. Adv., 2020, 6, eaay7685. 10.1126/sciadv.aay7685
- A. Provino, V. Smetana, T. Hackett, D. Paudyal, M. Kashyap, C. Bernini, A. Bhattacharyya, S. Dhar, M. Pani, F. Gatti, A.-V. Mudring, P. Manfrinetti, Stability, crystal-chemistry and magnetism of U2+xNi21−xB6 and Nb3−yNi20+yB6 and the role of U in the formation of the quaternary U2−zNbzNi21B6 and UδNb3−δNi20B6 systems. Inorg. Chem., 2019, 58, 15045–15059. 10.1021/acs.inorgchem.9b01440
- G. Wang, M. Valldor, K. Dorn, M. Wilk-Kozubek, V. Smetana, A.-V. Mudring, Ionothermal Synthesis Enables Access to 3D Open Framework Manganese Phosphates Containing Extra-Large 18-Ring Channels. Chem. Mater., 2019, 31, 7329–7339. 10.1021/acs.chemmater.9b01935
- G. Wang, M. Valldor, S. Siebeneichler, M. Wilk-Kozubek, V. Smetana, A.-V. Mudring, Ionothermal Synthesis, Structures, and Magnetism of Three New Open Framework Iron Halide-Phosphates. Inorg. Chem., 2019, 58, 13203–13212. 10.1021/acs.inorgchem.9b02028
- D. Chand, M. Wilk-Kozubek, V. Smetana, A.-V. Mudring, Alternative to the Popular Imidazolium Ionic Liquids: 1,2,4-Triazolium Ionic Liquids with Enhanced Thermal and Chemical Stability. ACS Sust. Chem. Eng., 2019, 7, 15995–16006. 10.1021/acssuschemeng.9b02437
- V. Smetana, M. Wilk-Kozubek, A.-V. Mudring, Active-Transition-Metal Tellurides: Through Crystal Structures to Physical Properties. Cryst. Growth Des., 2019, 19, 5429–5440. 10.1021/acs.cgd.8b01582
- N. Sangeetha, L.-L. Wang, A. Smirnov, V. Smetana, A.-V. Mudring, D. Johnson, M. Tanatar, R. Prozorov, D. Johnston, Helical antiferromagnetic ordering in EuNi1.95As2 single crystals. Phys. Rev. B, 2019, 100, 094447. 10.1103/PhysRevB.100.094447
- N. Sangeetha, V. Smetana, A.-V. Mudring, D. Johnston, Helical antiferromagnetic ordering in EuNi1.95As2 single crystals. Phys. Rev. B, 2019, 100, 094438. 10.1103/PhysRevB.100.094438
- J. Liu, Y. Mudryk, V. Smetana, A.-V. Mudring, V.Pecharsky, Anomalous effects of Sc substitution and processing on magnetism and structure of (Gd1−xScx)5Ge4. J. Magn. Magn. Mater., 2019, 474, 482–492. 10.1016/j.jmmm.2018.11.004
- T. Bell, C. Celania, V. Smetana, A.-V. Mudring, G. Meyer, Tb3Pd2, Er3Pd2 and Er6Co5-x: structural variations and bonding in rare-earth-richer binary intermetallics. Acta Crystallogr. C., 2018, 74, 991–996. 10.1107/S2053229618010549
- M. Rhodehouse, T. Bell, V. Smetana, A.-V. Mudring, G. Meyer, From the Nonexistent Polar Intermetallic Pt3Pr4 via Pt2–xPr3 to Pt/Sn/Pr Ternaries. Inorg. Chem., 2018, 57, 9949–9961. 10.1021/acs.inorgchem.8b01121
- M. Rhodehouse, T. Bell, V. Smetana, A.-V. Mudring, G. , An Obscured or Nonexistent Binary Intermetallic, Co7Pr17, Its Existent Neighbor Co2Pr5, and Two New Ternaries in the System Co/Sn/Pr, CoSn3Pr1–x, and Co2–xSn7Pr3. Cryst. Growth Des., 2018, 18, 6273–6283. 10.1021/acs.cgd.8b01141
- N. Sangeetha, V. Anand, E. Cuervo-Reyes, V. Smetana, A.-V. Mudring, D. Johnston, Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet EuCo2−yAs2. Phys. Rev. B, 2018, 97, 144403. 10.1103/PhysRevB.97.144403
- J. Namanga, N. Gerlitzki, V. Smetana, A.-V. Mudring, Supramolecularly-caged green emitting ionic Ir(III)-based complex with fluorinated C^N ligands and its application in light emitting electrochemical cells. Appl. Mater. Interfaces, 2018, 10, 11026–11036. 10.1021/acsami.7b18159
- C. Celania, V. Smetana, A. Provino, P. Manfrinetti, A.-V. , R14(Au, M)51 (R = Y, La-Nd, Sm-Tb, Ho, Er, Yb, Lu; M = Al, Ga, Ge, In, Sn, Sb, Bi): Stability Ranges and Site Preference in the Gd14Ag51 Structure Type. Cryst. Growth Des., 2018, 18, 993–1001. 10.1021/acs.cgd.7b01469
- V. Smetana, Y. Mudryk, V. Pecharsky, A.-V. Mudring, Controlling magnetism via transition metal exchange in the series of intermetallics Eu(T1,T2)5In (T = Cu, Ag, Au). J. Mat. Chem. C, 2018, 6 1353–1362. 10.1039/C7TC04964A
- C. Celania, V. Smetana, A.-V. Mudring, Bringing order to large-scale disordered complex metal alloys: Gd2Au15−xSbx and BaAuxGa12−x. CrystEngComm, 2018, 20, 348–355. 10.1039/c7ce01865g
- N. Sangeetha, V. Smetana, A.-V. Mudring, D. Johnston, Antiferromagnetism in semiconducting SrMn2Sb2 and BaMn2Sb2 single crystals. Phys. Rev. B, 2018, 97 014402. 10.1103/PhysRevB.97.014402
- N. Sangeetha, V. Smetana, A.-V. Mudring, D. Johnston, Anomalous Composition-Induced Crossover in the Magnetic Properties of the Itinerant-Electron Antiferromagnet Ca1−xSrxCo2−yAs2. Phys. Rev. Lett., 2017, 119, 257203. 10.1103/PhysRevLett.119.257203
- V. Smetana, M. Rhodehouse, G. Meyer, A.-V. Mudring, Gold Polar Intermetallics: Structural Versatility through Exclusive Bonding Motifs. Acc. Chem. Res., 2017, 50, 2633–2641. 10.1021/acs.accounts.7b00316
- M. Di Marcantonio, J. Namanga, V. Smetana, N. Gerlitzki, F. Vollkommer, A.-V. Mudring, G. Bacher, E. Nannen. Green-yellow emitting hybrid light emitting electrochemical cell. J. Mater. Chem. C, 2017, 5, 12062–12068. 10.1039/C7TC02976D
- C. Celania, V. Smetana, A.-V. Mudring. Crystal structures and new perspectives on Y3Au4 and Y14Au51. Acta Crystallogr. C, 2017, 73, 692–696. 10.1107/S2053229617011068
- M. Li, V. Smetana, M. Wilk-Kozubek, Y. Mudryk, T. Alammar, V. Pecharsky, A.-V. Mudring, Open-Framework Manganese(II) and Cobalt(II) Borophosphates with Helical Chains: Structures, Magnetic, and Luminescent Properties. Inorg. Chem., 2017, 56, 11104–11112. 10.1021/acs.inorgchem.7b01423
- C. Celania, V. Smetana, A. Provino, V. Pecharsky, P. Manfrinetti, A.-V. Mudring, R3Au9Pn (R = Y, Gd, Tb, Dy, Ho; Pn = Sb, Bi): A Link between Cu10Sn3 and Gd14Ag51. Inorg. Chem., 2017, 56, 7247–7256. 10.1021/acs.inorgchem.7b00898
- D. Prodius, V. Smetana, S. Steinberg, M. Wilk-Kozubek, Y. Mudryk, V. Pecharsky, A.-V. Mudring, Breaking the paradigm: Record quindecim charged magnetic ionic liquids. Mater. Horiz., 2017, 4, 217–221. 10.1039/C6MH00468G
- I. Bigun, S. Steinberg, V. Smetana, Y. Mudryk, Y. Kalychak, L. Havela, V. Pecharsky, A.-V. Mudring, Magnetocaloric Behavior in Ternary Europium Indides EuT5In: Probing the Design Capability of First-Principles-Based Methods on the Multifaceted Magnetic Materials. Chem. Mater., 2017, 29, 2599–2614. 10.1021/acs.chemmater.6b04782
- I. Bigun, V. Smetana, Y. Mudryk, I. Hlova, M. Dzevenko, L. Havela, Y. Kalychak, V. Pecharsky, A.-V. Mudring, EuNi5InH1.5−x (x = 0–1.5): hydrogen induced structural and magnetic transitions. J. Mater. Chem. C, 2017, 5, 2994–3006. 10.1039/C7TC00121E
- V. Smetana, S. Steinberg, A.-V. Mudring, Layered Structures and Disordered Polyanionic Nets in the Cation-Poor Polar Intermetallics CsAu1.4Ga2.8 and CsAu2Ga2.6. Cryst. Growth Des., 2016, 17, 693–700. 10.1021/acs.cgd.6b01536
- V. Smetana, A.-V. Mudring, Cesium platinide hydride 4Cs2Pt×CsH: an intermetallic double salt featuring metal anions. Angew. Chem. Int. Ed., 2016, 55, 14838–14841. 10.1002/anie.201606682
- A. Provino, S. Steinberg, V. Smetana, U. Paramanik, P. Manfrinetti, S. K. Dhar, A.-V. Mudring, Gold in the layered structures of R3Au7Sn3: From relativity to versatility. Cryst. Growth Des., 2016, 16, 5657–5668. 10.1021/acs.cgd.6b00478
- A. Provino, N. S. Sangeetha, S. K. Dhar, V. Smetana, K. A. Gschneidner Jr., V. K. Pecharsky, P. Manfrinetti, A.-V. Mudring, New R3Pd5 compounds (R = Sc, Y, Gd–Lu): formation and stability, crystal structure and antiferromagnetism. Cryst. Growth Des., 2016, 16, 6001–6015. 10.1021/acs.cgd.6b01045
- A. Provino, V. Smetana, D. Paudyal, K. A. Gschneidner Jr., A.-V. Mudring, V. K. Pecharsky, P. Manfrinetti, M. Putti, Gd3Ni2 and Gd3CoxNi2-x: magnetism and unexpected Co/Ni crystallographic ordering. J. Mat. Chem. C, 2016, 4, 6078–6089. 10.1039/C6TC01035K
- V. Smetana, S. Steinberg, Y. Mudryk, V. Pecharsky, G. J. Miller, A.-V. Mudring, Cation-poor complex metallic alloys in Ba(Eu)-Au-Al(Ga) systems: identifying the keys that control structural arrangements and atom distribution at the atomic level. Inorg. Chem., 2015, 54, 10296–10308. 10.1021/acs.inorgchem.5b01633
- A. Provino, S. Steinberg, V. Smetana, R. Kulkarni, S. Dhar, P. Manfrinetti, A.-V. Mudring, Gold-rich R3Au7Sn3: establishing the interdependence between electronic features and physical properties. J. Mat. Chem. C, 2015, 3, 8311–8321. 10.1039/C5TC00884K
- V. Smetana, S. Steinberg, N. Card, A.-V. Mudring, G. J. Miller, Crystal Structure and Bonding in BaAu5Ga2 and AeAu4+xGa3−x (Ae = Ba and Eu): Hexagonal diamond-type Au frameworks and remarkable cation/anion partitioning in the Ae−Au−Ga systems. Inorg. Chem., 2015, 54, 1010–1018. 10.1021/ic502402y
- V. Smetana, L. Kienle, V. Duppel, A. Simon, Synthesis, Crystal Structure, and TEM Analysis of Sr19Li44 and Sr3Li2: A reinvestigation of the Sr–Li phase diagram. Inorg. Chem., 2015, 54, 733–739. 10.1021/ic5010165
- V. Smetana, J. D. Corbett, G. J. Miller, MgAuGa and MgAu2Ga: first representatives of the Ma–Au–Ga system. Acta Crystallogr. C, 2014, 70 355. 10.1107/S205322961400566X
- V. Levytskyy, V. Babizhetskyy, B. Kotur, V. Smetana, Diterbium heptanickel: a crystal structure redetermination. Acta Crystallogr. E, 2014, 70, i42. 10.1107/S1600536814015384
- V. Smetana, J. D. Corbett, G. J. Miller, Complex polyanionic nets in RbAu4.01Ga8.64 and CsAu5Ga9: the role of cations in the formation of new polar intermetallics. Z. Anorg. Allg. Chem., 2014, 640, 790–796. 10.1002/zaac.201400015
- V. Levytskyy, V. Babizhetskyy, B. Kotur, V. Smetana, Redetermination of Dy3Ni from single-crystal X-ray data. Acta Crystallogr. E, 2013, 26, i80. 10.1107/S1600536813028717
- C. Xiao, L. Wang, R. Maligal-Ganesh, V. Smetana, H. Walen, P. Thiel, G. J. Miller, D. Johnson, W. Huang, Intermetallic NaAu2 as a heterogeneous catalyst for low temperature CO oxidation. J. Am. Chem. Soc., 2013, 135, 9592–9595. 10.1021/ja403175c
- V. Smetana, J. Corbett, G. Miller, Polyclusters and Substitution Effects in the Na-Au-Ga System: remarkable Sodium Bonding Characteristics in Polar Intermetallics. Inorg. Chem., 2013, 52, 12502–12510. 10.1021/ic401580y
- V. Smetana, J. Corbett, G. Miller, Na8Au10Ga7 and Na17Au5.9Ga46.6: The diversity of 5-fold Symmetries in the Na–Au–Ga System. J. Solid State Chem., 2013, 207, 21–28. 10.1016/j.jssc.2013.08.017
- J. Liu, V. Smetana, K. Gschneidner, G. Miller, V. Pecharsky, The crystal structure and magnetic properties of Pr117Co56.7Ge112. J Appl. Phys., 2013, 113, 17E120. 10.1063/1.4794376
- C. Wang, J. Zou, J. Liu, Y. Mudryk, K. Gschneidner, Y. Long, V. Smetana, G. Miller, V. Pecharsky, Crystal structure, magnetic properties and the magnetocaloric effect of Gd5Rh4 and GdRh. J Appl. Phys., 2013, 113 17A904. 10.1063/1.4793775
- Y. Mudryk, P. Manfrinetti, V. Smetana, J. Jiu, A. Provino, V. Pecharsky, G. Miller, K. Gschneidner, Structural disorder and magnetism in rare-earth (R) R117Co54+xSn112+y. J Alloys Compd., 2013, 557, 252–260. 10.1016/j.jallcom.2012.12.137
- V. Levytskyy, V. Babizhetskyy, B. Kotur, V. Smetana, Redetermination of dysprosium trinickel from single-crystal X-ray data. Acta Crystallogr. E, 2012, 68, i83. 10.1107/S1600536812043747
- V. Smetana, Q. Lin, D. Pratt, A. Kreyssig, M. Ramazanoglu, J. Corbett, A. Goldman, G. Miller, A Sodium-Containing Quasicrystal: Using Gold to Enhance Sodium’s Covalency in Intermetallics. Angew. Chem. Int. Ed., 2012, 51, 12699–12702. 10.1002/anie.201207076
- Q. Lin, V. Smetana, G. Miller, J. Corbett, Conventional and stuffed Bergman-type phases in the Na-Au-T (T = Ga, Ge, Sn) systems: Synthesis, structures, coloring of cluster centers, and Fermi sphere-Brillouin zone interactions. Inorg. Chem., 2012, 51, 8882–8889. 10.1021/ic300866q
- V. Smetana, G. Miller, J. Corbett, Three alkali-metal-gold-gallium systems. Ternary tunnel structures and some problems with poorly ordered cations. Inorg. Chem., 2012, 51, 7711–7721. 10.1021/ic300740u
- A. Provino, Y. Mudryk, D. Paudyal, V. Smetana, P. Manfrinetti, V. Pecharsky, Jr. Gschneidner, J. Corbett, Crystal structure of Tb5Ni2In4 and Y5Ni2In4, and magnetic properties of Dy5Ni2In4. J. Appl. Phys., 2012, 111, 07E122. 10.1063/1.3673432
- V. Levytskyy, V. Babizhetskyy, B. Kotur, V. Smetana, Didysprosium hepta-nickel. Acta Cryst E, 2012, 68, i20. 10.1107/S1600536812007611
- V. Smetana, J. Corbett, G. Miller, Four polyanionic compounds in the K-Au-Ga system: A case study in exploratory synthesis and of the art of structural analysis. Inorg. Chem., 2012, 51, 1695–1702. 10.1021/ic201999u
- I. Bigun, V. Smetana, Y. Kalychak, A new rhombohedral modification of EuNi5In. Acta Crystallogr. C, 2011, 67, i42. 10.1107/S0108270111022359
- V. Smetana, G. Vajenine, L. Kienle, V. Duppel, A. Simon, Intermetallic and metal-rich phases in the system Li-Ba-In-N. J. Solid State Chem., 2010, 183, 1767–1775. 10.1016/j.jssc.2010.05.021
- V. Smetana, A. Simon, Synthesis and crystal structure of barium indide Ba9In4. Z. Naturforsch. B, 2010, 65, 643–645. 10.1515/znb-2010-0517
- L. Kienle, V. Smetana, V. Duppel, A. Simon, Electron Microscopy Investigation on Highly Beam and Moisture sensitive Samples – the System Li/Ba/Ca. Z. Anorg. Allg. Chem., 2010, 636, 325–330. 10.1002/zaac.200900335
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon, Darstellung und Kristallstruktur der Phasen Li26Na58Ba38Ex (E = N, H; x = 0–1). Z. Anorg. Allg. Chem., 2008, 634, 849–852. 10.1002/zaac.200700520
- V. Smetana, V. Babizhetskyy, A. Simon, LixNayBa14LiN6: New Representatives of the Subnitride Family. Z. Anorg. Allg. Chem., 2008, 634, 629. 10.1002/zaac.200700472
- V. Smetana, V. Babizhetskyy, C. Hoch, A. Simon, Icosahedral Li-Clusters in the Structures of Li33.3Ba13.1Ca3 and Li18.9Na8.3Ba15.3. J. Solid State Chem., 2007, 180, 3302. 10.1016/j.jssc.2007.09.024
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon, Synthesis and Crystal Structure of the New Quaternary Subnitride Na15Li8Ba12N6. Z. Anorg. Allg. Chem., 2007, 633, 2296. 10.1002/zaac.200700192
- V. Smetana, V. Babizhetskyy, G. Vajenine, C. Hoch, A. Simon, Double-Icosahedral Li Clusters in a New Binary Compound Ba19Li44: A Reinvestigation of the Ba-Li Phase Diagram. Inorg. Chem., 2007, 46, 5425. 10.1021/ic070249i
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon, Synthesis and crystal structure of LiBa2N and identification of LiBa3N. J. Solid State Chem., 2007, 180, 1889. 10.1016/j.jssc.2007.04.012
- V. Smetana, V. Babizhetskyy, C. Hoch, A. Simon, Refinement of the crystal structure of barium tetralithium, BaLi4. Z. Kristallogr. NCS, 2006, 221, 434. 10.1524/ncrs.2006.0142
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon, Li80Ba39N9: The First Li/Ba Subnitride. Inorg. Chem., 2006, 45, 10786. 10.1021/ic0613816
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon, Li26 Clusters in the Compound Li13Na29Ba19. Angew. Chem. Int. Ed., 2006, 45, 6051. 10.1002/anie.200602137
- S. Chykhrij, V. Smetana, Phase relations in the Pr-Fe-Sb and Pr-Co-Sb systems. Inorg. Mat., 2006, 42, 503. 10.1134/S0020168506050104
- S. Chykhrij, V. Smetana, Phase equilibria and crystal structures of the compounds in the Pr-Ni-Sb system at 870K. J Alloys Compd., 2005, 400, 100. 10.1016/j.jallcom.2005.03.049
Refereed Conference Proceedings
- A. Provino, A. Pathak, V. Pecharsky, M. Putti, C. Ferdeghini, V. Smetana, A. Mudring, P. Manfrinetti, Effect of chemical and physical pressure on the superconducting properties of LaZn2-xSn2 Bull. Am. Phys. Soc. 2018
- G. Miller, S. Thimmaiah, V. Smetana, A. Palasyuk, Q. Lin, Gold’s structural versatility within complex intermetallics: from Hume-Rothery to Zintl and even quasicrystals. MRS Proceedings 2013, 1517
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon, Neue Li26-cluster in Li13Na29Ba19. Anorg. Allg. Chem., 2006, 632, 2115
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon, Li80Ba39N9: Ein erstes Li-Ba subnitrid. Z. Anorg. Allg. Chem., 2006, 632, 2114
Invited Talks
- Smetana, J. Corbett, G. Miller “Crystal structures and electronic properties in the Na–Au–Ga system: crystal structure and electronic properties.”
Gordon research conference, New London (July, 2012) [Invited Poster with oral presentation]
Contributed Presentations
- T. Bell, V. Smetana, A.-V. Mudring, G. Meyer ”The hidden island of rare earth rich intermetallics.” Terrae Rarae, Stockholm, Sweden-Helsinki, Finland (2019) [Oral presentation].
- A. Provino, A. Pathak, V. Pecharsky, M. Putti, C. Ferdeghini, V. Smetana, A. Mudring, P. Manfrinetti “Effect of chemical and physical pressure on the superconducting properties of LaZn2-xSn2.” APS March Meeting, Los Angeles (CA), USA (2018) [Oral presentation].
- A. Provino, A. Pathak, V. Smetana, A. Mudring, M. Putti, C. Ferdeghini, V.K. Pecharsky and P. Manfrinetti “LaZn2-xSn2: unusual superconductivity in a new 1:2:2 crystallographically disordered compound.” 62th Annual Conference on Magnetism and Magnetic Materials, Pittsburgh (PA), USA (2017) [Oral presentation].
- A. Provino, A. Pathak, V. Smetana, A.-V. Mudring, V. Pecharsky, M. Putti, C. Ferdeghini, P. Manfrinetti “LaZn2-xSn2: unusual superconductivity in a new crystallographically disordered 1:2:2 compound.” Muroran-IT Rare Earth Workshop, Kasumigaseki, Tokyo, Japan (2017) [Oral presentation and Poster].
- M. Pani, A. Provino, V. Smetana, P. Manfrinetti “Crystal chemistry of new rare earth nickel silicides.” 28th Rare Earth Research Conference, Ames (IA), USA (2017) [Oral Presentation].
- V. Smetana, Y. Mudryk, V. Pecharsky, A.-V. Mudring ”Structural Variations and Magnetism in the Transition-Metal-Rich Intermetallics Eu(T1,T2)5In (T = Cu, Ag, Au).” 28th Rare Earth Research Conference, Ames (IA), USA (2017) [Poster].
- D. Prodius, V. Smetana, S. Steinberg, M. Wilk-Kozubek, Y. Mudryk, V. Pecharsky, A.-V. Mudring ”Breaking the paradigm: record quindecim {15+} charged magnetic ionic liquids.” 28th Rare Earth Research Conference, Ames (IA), USA (2017) [Poster].
- A. Provino, V. Pecharsky, V. Smetana, C. Ritter, A.-V. Mudring, P. Manfrinetti “Crystallographic ordering and magnetic structure in the next-to-ternary RCo1–xNix compounds (R = Gd–Lu).” 28th Rare Earth Research Conference, Ames (IA), USA (2017) [Poster].
- M. Rhodehouse, V. Smetana, G. Miller, A.-V. Mudring, G. Meyer “In search of new rare-earth rich intermetallics.” 28th Rare Earth Research Conference, Ames (IA), USA (2017) [Poster].
- C. Celania, V. Smetana, A. Provino, P. Manfrinetti, V. Pecharsky, A.-V. Mudring “R3Au9Pn (R = Y, Gd, Tb, Dy, Ho; Pn = Sb, Bi): A link between Cu10Sn3 and Gd14Ag51.” 28th Rare Earth Research Conference, Ames (IA), USA (2017) [Poster].
- V. Smetana, Y. Mudryk, A. Mudring, V. Pecharsky and K.A. Gschneidner “Evolution of crystal structure and magnetic properties with the variation of Cu/Au ratio in the Eu(Cu,Au)5In solid solution.” 13th Joint MMM-Intermag Conference / Magneto-Optic, Magnetoelastic, and Magnetocaloric Materials, San Diego (CA), USA (2016) [Poster].
- A. Provino, P. Manfrinetti, V. Smetana, M. Putti, D. Paudyal, K. Gschneidner, Jr. “Crystal structure and ferromagnetism of Gd3Ni2 and Gd3(CoxNi1–x)2.” American Physical Society Meeting, Denver (CO), USA (2014) [Poster].
- A. Provino, S. Dhar, V. Smetana, K. Gschneidner Jr., M. Khan, P. Manfrinetti, C. Ferdeghini “Ferromagnetism in R5Co3Ni2 compounds (R = Gd, Tb, Dy, Ho, Er). 59th Conference on Magnetism and Magnetic Materials, Honolulu (HI), USA (2014) [Poster].
- J. Liu, V. Smetana, K. A. Gschneidner, Jr., G. J. Miller, and V. K. Pecharsky “The crystal structure and magnetic properties of Pr117Co56.7Ge112.” 12th Joint MMM-Intermag Conference / Magneto-Optic, Magnetoelastic, and Magnetocaloric Materials, Chicago (IL), USA (2013) [Poster].
- C. L. Wang, J. D. Zou, J. Liu, Y. Mudryk, K. A. Gschneidner, Jr., Y. Long, V. Smetana, G. J. Miller, and V. K. Pecharsky “Crystal structure, magnetic properties, and the magnetocaloric effect of Gd5Rh4and GdRh.” 12th Joint MMM-Intermag Conference / Magneto-Optic, Magnetoelastic, and Magnetocaloric Materials, Chicago (IL), USA (2013) [Poster].
- V. Smetana, J. Corbett, G. Miller “Crystal structures and electronic properties in the Na–Au–Ga system: crystal structure and electronic properties.” Gordon research conference, New London (NH), USA (2012) [Oral presentation and Poster].
- G. J. Miller, S. Thimmaiah, V. Smetana, A. Palasyuk, Q. Lin “Gold’s structural versatility within complex intermetallics: From Hume-Rothery to Zintl Phases and even quasicrystals” MRS Fall Meeting, Boston (MA), USA (2012) [Oral Presentation].
- A. Provino, Y. Mudryk, D. Paudyal, V. Smetana, P. Manfrinetti, V. K. Pecharsky, K. A. Gschneidner Jr., J. D. Corbett “Crystal structure of Tb5Ni2In4 and Y5Ni2In4 and magnetic properties in Dy5Ni2In4.” 56th Annual Conference on Magnetism and Magnetic Materials, Scottsdale (AZ), USA (2011) [Oral Presentation].
- V. Smetana, V. Duppel, L. Kienle, A. Simon “Electron microscopy investigations in the system Li–Ba–Ca.” 17th Jahrestagung der Deutschen Gesellschaft für Kristallographie, Hannover, Germany (2009) [Poster].
- V. Smetana “Subnitride with Lithium. Electron Microscopy.” Hemdsaermelkolloqium, Marburg, Germany (2009) [Oral Presentation].
- V. Smetana, V. Babizhetskyy, G. Vajenine, C. Hoch, A. Simon “Phase relationship with Li/Ba subnitrides and intermetallic compounds.” Xth International Conference on Crystal Chemistry of Intermetallic Compounds, Lviv, Ukraine (2007) [Oral Presentation].
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon “Synthesis and Crystal Structure of the new quaternary subnitride Na15Li8Ba12N6” Xth International Conference on Crystal Chemistry of Intermetallic Compounds, Lviv, Ukraine (2007) [Poster].
- V. Smetana, V. Babizhetskyy, G. Vajenine, C. Hoch, A. Simon “Novel ionic and metallic subnanostructures in Li-rich compounds.” GDCh Wissenschaftsforum Chemie, Ulm, Germany (2007) [Poster]. International Karlsruhe Nanoscience Workshop „Metal-rich Compounds”, Karlsruhe, Germany (2007) [Poster].
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon “Double-icosahedral Li clusters in a new binary compound Ba19Li44.” XIth European Conference On Solid State Chemistry, Caen, France (2007) [Poster]
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon “Synthesis and crystal structures of LiBa2N and LiBa3N” XIth European Conference On Solid State Chemistry, Caen, France (2007) [Poster]
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon “Neue Li26-Cluster in Li26Na29Ba19” 13. GDCh Conference, Aachen, Germany (2006) [Poster].
- V. Smetana, V. Babizhetskyy, G. Vajenine, A. Simon “Li80Ba39N9: Ein erstes Li-Ba-Subnitrid” 13. GDCh Conference, Aachen, Germany (2006) [Poster].